Wednesday, October 13, 2010

Airplanes - B.O.B lyrics

Can we pretend that airplanes In the night sky Are like shooting stars I could really use a wish right now (wish right now, wish right now) Can we pretend that airplanes In the night sky Are like shooting stars I could really use a wish right now (wish right now, wish right now)





Yeah I could use a dream or a genie or a wish To go back to a place much simpler than this Cause after all the partyin' and smashin' and crashin' And all the glitz and the glam and the fashion And all the pandemonium and all the madness There comes a time where you fade to the blackness And when you're staring at that phone in your lap And you hoping but them people never call you back But that's just how the story unfolds You get another hand soon after you fold And when your plans unravel And they sayin' what would you wish for If you had one chance So airplane airplane sorry I'm late I'm on my way so don't close that gate If I don't make that then I'll switch my flight And I'll be right back at it by the end of the night





Can we pretend that airplanes In the night sky Are like shooting stars, I could really use a wish right now (wish right now, wish right now) Can we pretend that airplanes In the night sky Are like shooting stars I could really use a wish right now (wish right now, wish right now)





Somebody take me back to the days Before this was a job, before I got paid Before it ever mattered what I had in my bank Yeah back when I was tryin' to get into the subway And back when I was rappin' for the hell of it But now a days we rappin' to stay relevant I'm guessin that if we can make some wishes outta airplanes Then maybe yo maybe I'll go back to the days Before the politics that we call the rap game And back when ain't nobody listened to my mix tape And back before I tried to cover up my slang But this is for the Cada, what's up Bobby Ray So can I get a wish to end the politics And get back to the music that started this sh-t So here I stand and then again I say I'm hopin' we can make some wishes outta airplanes





Can we pretend that airplanes In the night sky Are like shooting stars I could really use a wish right now (wish right now, wish right now) Can we pretend that airplanes In the night sky Are like shooting stars I could really use a wish right now (wish right now, wish right now)

Monday, September 20, 2010

21 sept 2010

days left counted ..
time passed away by my regret..

I love you vainly..

In the place of nowhere,

Here i flashing back

Where i run away from you,

Give u unjustice feeling..



I take a breath deeply now..

You were gone away from my life

And if you can see my heart beating, theres only you...
Although i convince my self theres no you.. But only end in vain..

I love you

But now its too late to say i love you

In the place of nowhere

Monday, September 6, 2010

BDD (Body Dysmorphic Disorder)

Lana is looking at the mirror , she looking at the pretty face and lovely that staring back at her. she's smile but with 2 seconds that smile now turns into an angry face. now the reflection say that she is so unsatisfy for what she looks like..

yet Lana has 13 times beauty surgery in her life. everybody says that she is a perfect girls. and also she is a famous supermodel. so what makes she feeling so unhappy for her looks?

that's BDD

Body dysmorphic disorder.
Body dysmorphic disorder (BDD) (previously known as dysmorphophobia is sometimes referred to as body dysmorphia or dysmorphic syndrome) is a psychological somatoform disorder in which the affected person is excessively concerned about and preoccupied by a perceived defect in his or her physical featuresbody image). Depending on the individual case, BDD may either be a somatoform disorder or part of an eating disorder or both: BDD always includes a debilitating or excessive fear of judgment by others, as is seen with social anxiety social phobia and some problems; or, alternately, it may be a part of eating disorders such as norexia nervosa bulimia nervosa compulsive overeating. The term "body dysmorphic disorder" itself describes only those excessive social-acceptance fears that relate to one's personal body image. Depending on the individual, it may or may not also be part of one of these wider or related syndromes.

The disorder generally is diagnosed in those who are extremely critical of their mirror image, physique or self-image, even though there may be no noticeable disfigurement or defect. The three most common areas that those suffering from BDD will feel critical of have to do with the face: the hair, the skin, and the nose. Outside opinion will typically disagree and may protest that there even is a defect. The defect exists in the eyes of the beholder, and one with BDD really does feel as if they see something there that is defective.

People with BDD say that they wish that they could change or improve some aspect of their physical appearance even though they are generally of normal or even highly attractive appearance. Body dysmorphic disorder causes sufferers to believe that they are so unspeakably hideous that they are unable to interact with others or function normally for fear of ridicule and humiliation about their appearance. This can cause those with this disorder to begin to seclude themselves or have trouble in social situations. More extreme cases may cause a person to develop love-shyness, a chronic avoidance of all intimate relationships. They can become secretive and reluctant to seek help because they fear that others will think them vain or because they feel too embarrassed. It has been suggested that fewer men seek help for the disorder than women.

People with BDD never be happy . altough she has a good looking and great life. thats what Lana feel.

Tuesday, June 8, 2010

UTS KIMIA ORGANIK

Download soal

UAS 1 KIMIA ORGANIK 2

UJIAN TENGAH SEMESTER

KIMIA ORGANIK 2



1

Write a structural formula for each one.

a. 5-isopropenyl-2-methyl-2-cyclohexenone

b. 4-hydroxy-4-methyl-2-pentanone

c. 2-Hydroxypropanoic acid

d. 10-Undecenoic acid

2

a. Predict the product of the reaction of propanal with Sodium cyanide with addition of sulfuric acid

b. Predict the product of the reaction of cyclopentanone with Hydrazine

c. Give the product of the reaction of pentanoic acid with reagent of Phenylmagnesium bromide

d. Give the product of the reaction of 2-(p-Isobutylphenyl)propanoic acid with reagent of Phosphorus tribromide

3

a.

b.

c.

d.

4

Wolff–Kishner reduction (hydrazine, KOH, ethylene glycol, 130°C) of the compound shown gave compound A. Treatment of compound A with m-chloroperoxybenzoic acid gave compound B, which on reduction with lithium aluminum hydride gave compound C. Oxidation of compound C with chromic acid gave compound D (C9H14O). Identify compounds A through D in this sequence.

5

Show by a series of equations how you could synthesize each of the following compounds from the indicated starting material and any necessary organic or inorganic reagents:

a. 2-Methylpropanoic acid from tert-butyl alcohol

b. HO2C(CH2)5CO2H from HO2C(CH2)3CO2H

c. from cyclopentyl bromide